姓名：徐浩（博士生导师）
系别：河南大学化学化工学院化学系
职称：教授
院内职务：化学系副主任、有机教研室主任
邮箱：xuhao@poscoop.com
教育经历：
2009/9 - 2012/7，清华大学，有机化学，博士
2006/9 - 2009/7，北京化工大学，有机化学，硕士
2002/9 - 2006/7，天津大学，应用化学，学士
研究方向：
1. 光催化有机合成
2. 过渡金属催化杂环合成
3. 精细化学品合成工艺开发
主持项目：
1. 2023年河南省重点研发和推广专项，团簇修饰的氧化亚铜半导体材料在二氧化碳高值酰化转化中的关键技术研究
2. 2023年河南大学青年交叉基金一般项目，铁负载共价有机框架光催化剂的构筑及其在Ullmann偶联中的应用
3. 2020年横向项目，稠环荧光有机单体及聚合物的合成开发工艺
4. 2020年国家自然科学基金，新型共价有机框架材料的构筑及其在可见光诱导插入反应中的应用研究
5. 2020年河南大学一流学科培育项目，5-氨基乙酰丙酸盐酸盐新合成工艺研究
6. 2019年河南省高等学校青年骨干教师培养计划，窄带隙共价有机框架材料的设计及其在可见光促进芳基化反应中的催化性能研究
7. 2017年横向项目，5-氨基乙酸丙酸生产工艺开发
8. 2015年国家自然科学基金青年项目，以腈为底物的过渡金属催化氮杂环化合物新合成方法研究
9. 2014年河南大学优秀青年科研人才培育基金，氮杂环化合物的铜催化新合成方法研究
论文（第一或通讯作者）：
1. Z. Xu, Y, Xu, H. Xu,* H.Fu*. Visible Light-Promoted Goldberg Reaction Driven by a Preponderant Facet of CuO Nanocrystals. ACS Catal., 2023, 13, 13920−13930.
2. C. Wu, Q. Bian, H. Xu,* H. Li,* H. Fu*. Photoinduced Iron-Catalyzed ipso-Nitration of Aryl Halides via Single-Electron Transfer. ACS Catal., 2021, 11, 9561−9568 (封面).
3. J. Yuan, Q. Xia, X. Yang,* H. Xu,* Y. Xu*. Sunlight-Driven Synthesis of 1,2,4-Thiadiazoles via Oxidative Construction of a Nitrogen-Sulfur Bond Catalyzed by a Reusable Covalent Organic Framework. ChemPhotoChem, 2020, 4, 445–450.
4. Q. Bian, C. Wu, H. Xu,* Y. Xu.* Iron Nitrate-Mediated Selective Synthesis of 3‑Acyl-1,2,4-oxadiazoles from Alkynes and Nitriles: The Dual Roles of Iron Nitrate. J. Org. Chem., 2020, 85, 4058−4066 (封面).
5. Q. Xia, Z. Shi, X. Yang,* H. Xu.* Visible-Light-Enabled Selective Oxidation of Primary Alcohols through Hydrogen-Atom Transfer and its Application in the Synthesis of Quinazolinones. Asian J. Org. Chem., 2019, 8, 1933-1941.
6. S. Liu, W. Pan, S. Wu, X. Bu, S. Xin, J. Yu,* H. Xu,* X. Yang*. Visible-light-induced tandem radical addition-cyclization of 2-aryl phenyl isocyanides using recyclable covalent organic frameworks as photocatalysts. Green Chem., 2019, 21, 2905-2910.
7. Z. Lai, Z. Li, Y. Liu, P. Yang, X. Fang, W. Zhang, B. Liu, H. Chang, H. Xu,* Y. Xu*. Iron-mediated synthesis of isoxazoles from alkynes: Using iron(III) nitrate as a nitration and cyclization reagent. J. Org. Chem., 2018, 83, 145-153.
8. L. Chai, Z. Lai, Q. Xia, J. Yuan, Q. Bian, M. Yu, W. Zhang, Y. Xu,* H. Xu*. One-pot synthesis of 3-aryl-5-amino-1,2,4-thiadiazoles from imidates and thioureas by I2-mediated oxidative construction of the N–S bond. Eur. J. Org. Chem., 2018, 4338-4344.
9. P. Yang, Y. Liu, L. Chai, Z. Lai, X. Fang, B. Liu, W. Zhang, M. Lu, Y. Xu, H. Xu*. Nmp-based ionic liquids: Recyclable catalysts for both hetero-Michael addition and Knoevenagel condensation in water. Synth. Commun., 2018, 48, 1060-1067.
10. H. Su, L. Wang, H. Rao,* H. Xu*. Iron-catalyzed dehydrogenative sp3–sp2 coupling via direct oxidative C–H activation of acetonitrile. Org. Lett., 2017, 19, 2226-2229.
11. L. Pan, Z. Li, T. Ding, X. Fang, W. Zhang, H. Xu,* Y. Xu*. Base-mediated synthesis of unsymmetrical 1,3,5-triazin-2-amines via three-component reaction of imidates, guanidines, and amides or aldehydes. J. Org. Chem., 2017, 82, 10043-10050.
12. H. Li, J. Jie, S. Wu, X. Yang,* H. Xu*. Rh(III)-catalyzed direct C-7 amination of indolines with anthranils. Org. Chem. Front., 2017, 4, 250-254.
13. L. Chai, Y. Xu, T. Ding, X. Fang, W. Zhang, Y. Wang, M. Lu, H. Xu,* X. Yang*. One-pot synthesis of 3,5-disubstituted 1,2,4-thiadiazoles from nitriles and thioamides via I2-mediated oxidative formation of an N-S bond. Org. Biomol. Chem., 2017, 15, 8410-8417.
14. Y. Liu, Z. Lai, P. Yang, Y. Xu, W. Zhang, B. Liu, M. Lu, H. Chang, T. Ding,* H. Xu*. Thio-Michael addition of α,β-unsaturated amides catalyzed by Nmm-based ionic liquids. RSC Adv., 2017, 7, 43104-43113.
15. Z. Li,* D. Luo, M. Li, X. Xing, Z. Ma, H. Xu*. Recyclable Fe3O4 nanoparticles catalysts for aza-Michael addition of acryl amides by magnetic field. Catalysts, 2017, 7, 219.
16. H. Xu, L. Pan, X. Fang, B. Liu, W. Zhang, M. Lu, Y. Xu,* T. Ding*. Knoevenagel condensation catalyzed by novel Nmm-based ionic liquids in water. Tetrahedron Lett., 2017, 58, 2360-2365.
17. W. Wang, H. Xu,* Y. Xu,* T. Ding, W. Zhang, Y. Ren, H. Chang. Base-mediated one-pot synthesis of 1,2,4-oxadiazoles from nitriles, aldehydes and hydroxylamine hydrochloride without addition of extra oxidant. Org. Biomol. Chem., 2016, 14, 9814-9822.
18. H. Xu,* S. Ma, Y. Xu,* L. Bian, T. Ding, X. Fang, W. Zhang, Y. Ren. Copper-catalyzed one-pot synthesis of 1,2,4-triazoles from nitriles and hydroxylamine. J. Org. Chem., 2015, 80, 1789-1794.
19. H. Xu, Y. Jiang, H. Fu*. Copper-catalyzed synthesis of 1,2,4-triazoles via sequential coupling and aerobic oxidative dehydrogenation of amidines. Synlett, 2013, 24, 125-129.
20. H. Xu, H. Fu*. Copper-catalyzed one-pot synthesis of imidazo/benzoimidazoquinazolinones by sequential Ullmann-type coupling and intramolecular C-H amidation. Chem. Eur. J., 2012, 18, 1180-1186.
21. H. Xu, S. Li, H. Liu, H. Fu*, Y. Jiang*. Simple and efficient copper-catalyzed cascade synthesis of naphthols containing multifunctional groups under mild conditions, Chem. Commun., 2010, 46, 7617-7619.
